Spray area with aggressive carb cleaner after removing the bolts, (with good ventilation unless you want to be permanently loopy) and give them a nice whack with a hammer and blunt/dull chisel where the cylinder part of the "boot" meets the flange. You can also use a big flat ended punch against the end of the flange itself. Just don't try and wedge something in between the flange and the head and gouge up the gasket surface. I assume you're replacing them. Otherwise, leave them alone. The flange part has metal stiffener inside, so you can get a pretty solid whack against it. If you smack them in such a way as to make them try and move sideways, parallel to the gasket surface, they'll pop right off. Most really nasty non-sensor safe carb cleaners will soften just about anything. Usually, all it takes is one good whack and off they come.
The carb mounts/boots/spigots should be replaced if any signs of cracking/splitting/etc are found. They tend to be done in by UV, heat, and ozone. They need to be a polymer as they somewhat isolate the carbs from heat, vibration and provide an easy and effective seal and mounting point. Consider them an expendable part. If the carbs were solid mounted, the vibration would cause the fuel to become a froth in the bowls, causing no end of jetting woes. The heat would tend to boil the fuel as well. They do a lot more than just mount the carbs.